The progressive incorporation of renewable biomass resources, including carbohydrates, lignin, polysaccharides, etc. in the chemical industry is a game changing transition towards building a circular and sustainable chemical supply chain. However, controlling the selective conversion of these polyfunctional substrates is a grand challenge, which is currently limiting the great potential of biomass transformation to high value-added specialty chemicals such as bio-based products.
We have managed to develop a new process based on the synergy between a solid catalyst and sonochemistry, called sonocatalysis. The core of this approach relies on generating highly reactive radicals via the rapid cavitation under high-frequency sonochemical activation and simultaneously transferring them to the catalyst surface to control the selectivity of biomass reactions. Benefiting from its distinctive features, sonocatalysis allows for fine-tuning the reaction selectivity for the transformation of biomass-derive feedstocks to high value-added specialty chemicals and access to chemicals that are generally not reachable by conventional routes.
We introduce a novel nanostructured material design with multiple gas-stabilizing sites, engineered to function as cavitation nuclei and catalysts. This innovative design facilitates selective and efficient acoustic energy transfer directly to the catalyst surface, avoiding the undesired dissipation of acoustic energy into the bulk solution and demonstrating superior cavitation properties at lower acoustic pressure amplitudes. This significantly lowers the energy required for inertial cavitation by ~827% compared to conventional catalysts and pure water. Our work represents a significant advance in sonocatalytic systems, promising efficient energy use in industrial applications.